Effect of Digestion Method, Siderite Content, and Fizz Rating on Neutralization Potential of Overburden Samples

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Table 12. Acid-base account values (metric tons per 1000 metric tons) for 13 overburden samples compared to leachate pH and cumulative alkalinity (summed mg/l after each cycle) after 6 soxhlet cycles. Positive ABA values indicate an excess of NP suggesting the pH and alkalinity of the sample's leachate should be alkaline. If the ABA value is negative, the values represent a deficiency in NP and the leachate should be acidic.

Acid-base Account Values
Sample SobekHand BOILHand SobekAuto H2O2Hand H2O2Auto SobPerHand SoxhletpH CumulativeAlkalinity
metric tons CaCO3 equivalent per 1000 metric tons mg/l
Fe
1 67 86 8 13 4 17 8.8 583
2 59 87 12 16 6 18 8.2 606
3 57 81 5 11 4 9 8.0 601
4 461 791 -8 -1 -4 -11 4.8 -396
5 -77 -59 1471 -85 -2 -116 4.8 -7,807
Ca  
1 923 933 923 921 925 923 9.3 1,584
3 708 721 707 725 705 708 9.5 2,591
S                
3 -202 -202 -264 -248 -265 --- 2.3 -30,360
5 -61 -61 -70 -66 -72 --- 2.4 -7,233
Si
11 37 70 10 17 12 9 9.0 905
15 -8 91 -6 -7 -6 -27 2.3 -1,784
16 14 59 8 20 9 7 8.8 828
17 79 79 11 17 10 --- 8.4 519

1Indicate incorrect ABA predictions based on water quality for leaching test.

Effect of Digestion Method, Siderite Content, and Fizz Rating on Neutralization Potential of Overburden Samples